(Excuse the pun. I couldn't help myself.)
Toward the end of my photowalk a couple of weeks ago I passed by a fast-food restaurant. Peeking in through the window, I was struck by the way the light wrapped around this guy--it almost looked like a painting.
Technical info: Shot with a Nikon D40 and Nikkor 50mm f/1.4G lens, in manual exposure mode. Aperture f/8, shutter 1/400 sec, ISO 200. Post-processing in Aperture 3: straightened and cropped; curves for exposure adjustment and contrast.
Thoughts for improvement: The outside of the building may be a little hot--I can't quite make up my mind about that. I'm also not sure whether a horizontal crop might work better.